Which of the following orders is not correct?

The equation which is balanced and represents the correct product$(s)$ is:

Give the correct order of initials $T$ or $F$ for following statements. Use $T$ if statement is true and $F$ if it is false.
$(I)$ Sulphide ions react with $Na_2[Fe(CN)_5(NO)]$ to form a purple coloured compound $Na_4[Fe(CN)_5(NOS)]$. In the reaction,the oxidation state of iron changes.
$(II)$ $Pt(IV)$ compounds are relatively more stable than $Ni(IV)$ compounds.
$(III)$ The welding of magnesium can be done in the atmosphere of Helium.
$(IV)$ $LiAlH_4$ on hydrolysis will give $H_2$.

Select the incorrect statement.

The reaction of $K_3[Fe(CN)_6]$ with freshly prepared $FeSO_4$ solution produces a dark blue precipitate called Turnbull's blue. The reaction of $K_4[Fe(CN)_6]$ with $FeSO_4$ solution in the complete absence of air produces a white precipitate $X$,which turns blue in air. Mixing the $FeSO_4$ solution with $NaNO_3$,followed by a slow addition of concentrated $H_2SO_4$ through the side of the test tube,produces a brown ring.
Precipitate $X$ is:
$(A)$ $Fe_4[Fe(CN)_6]_3$
$(B)$ $Fe[Fe(CN)_6]$
$(C)$ $K_2Fe[Fe(CN)_6]$
$(D)$ $KFe[Fe(CN)_6]$
Among the following,the brown ring is due to the formation of:
$(A)$ $[Fe(NO)_2(SO_4)_2]^{2-}$
$(B)$ $[Fe(NO)_2(H_2O)_4]^{3+}$
$(C)$ $[Fe(NO)_4(SO_4)_2]$
$(D)$ $[Fe(H_2O)_5(NO)]SO_4$

Three arrangements are shown for the complex $[CoBr_2(NH_3)_2(en)]^{\oplus}$. Which one is the wrong statement?